N,N′-Bis(2,6-diethylphenyl)acenaphthylene-1,2-diimine
نویسندگان
چکیده
The title compound, C(32)H(32)N(2), has crystallographic twofold rotation symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the substituted benzene ring and the naphthalene ring system is 79.8 (1)°. The crystal structure is stabilized by C-H⋯N inter-actions, which form a chain motif along the b-axis direction.
منابع مشابه
Diacetonitrile[N,N′-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
The title compound, [CrCl(2)(CH(3)CN)(2)(C(26)H(36)N(2))]·CH(3)CN, was synthesized by the reaction of CrCl(2)(THF)(2) with N,N'-bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine in dichloro-methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chloride ions in a trans configuration with respect to each other, and by two N atoms of two acetoni...
متن کاملBis[N,N′-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]-1κ2 N,N′;2κ2 N,N′-tri-μ-trichlorido-1:2κ6 Cl:Cl-chlorido-1κCl-tetrahydrofuran-2κO-dichromium(II) dichloromethane 4.5-solvate
In the mol-ecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional te...
متن کاملBis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate
In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N'-bis-(di-2-pyridyl-methyl-eneamino)ethane-1,2-diimine ligands in a distorted tetra-hedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two ...
متن کاملN,N′-Bis[3,5-bis(2,6-diisopropylphenyl)phenyl]butane-2,3-diimine
The title mol-ecule, C(64)H(80)N(2), lies on an inversion center wherein the central butane-diimine fragment [N=C(Me)-C(Me)=N] is essentially planar [maximum deviation = 0.002 (2) Å] and its mean plane forms a dihedral of 70.88 (10)° with the attached benzene ring. In the symmetry-unique part of the mol-ecule, the dihedral angles between the benzene ring bonded to the N atom and the other two b...
متن کامل[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ2 N,N′]dibromidozinc
In the title compound, [ZnBr(2)(C(17)H(14)Cl(4)N(2))], the Zn(II) ion is bonded to two bromide ions and two N atoms of the diimine ligand and displays a moderately distorted tetra-hedral coordination geometry. The Schiff base ligand acts as a chelating ligand and coordinates to the Zn(II) atom via two N atoms.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012